The ssc of medium strength steels has been a continuing source of trouble in the oil fields, and from these troubles has evolved in international standards 6. It should not be confused with the term stress corrosion cracking which is an anodic cracking mechanism. Sulfide stress cracking nace mr01752002, mr0175iso 15156 651 te c h n i c a l new sulfide stress cracking standard for refineries don bush, principal engineer materials, at emerson process management fisher valves, is a member and former chair of a nace task group that has written a document for refinery applications, nace mr0103. Since strength of steel parallels its hardness, the empirically determined maximum hardness specified in rc22. Stress corrosion cracking behavior of nickel base alloys.
Water with hydrogen sulfide alone does not cause disease. When placed in proximity to tensile stresses, embrittlement and the beginnings of brittle fracture may occur. The chemistry of corrosion mechanism had been examined with the various types of corrosion and associated corroding agents in the oil and gas industry. This penetration can lead to the brittle fracture of materials that are normally ductile when hydrogen happens to be present in their environment. Corrosionpedia what is sulfide stress cracking ssc. Sulfide stress cracking ssc has been the subject of investigation since the late 1940s, when a mysterious form of brittle failure began to be observed in steel. Corrosion failure analysis southwest research institute. Polythionic acid stress corrosion cracking deterioration mechanisms heaters used in hydrodesulfurization, hydroforming, hydrocracking, and similar processes often have austenitic stainless steel tubes and usually process reactor feed or recycled. The history of nace mr0175, iso 15156, and the 1% nickel. Test frames for applying cyclic loads with the measurement of crack propagation rates. Sulfide stress cracking of nickelcontaining lowalloy steels. Sulfide stress crackingresistant drill pipe addresses h2s.
Ssc is a form of spontaneous brittle breakdown in occurring in highstrength alloys and steels when it comes in contact with humid hydrogen sulfide as well as sulfidic atmospheres. In addition to this, the offered array of services is rendered using the latest technology within the limited period of time. Stress corrosion cracking stainless steels are damaged by stress corrosion cracking in conditions containing chlorides at the high temperatures. The nace mr0175 standards metals for sulfide stress cracking and stress corrosion cracking resistance in sour oilfield environments. Us3585069a method of inhibiting sulfide cracking with a. In the hydroiodic acid at temperatures exceeding 177oc, alloy b2 was sensitive to transgranular stress corrosion cracking.
Environmental cracking is also known as caustic embrittlement, which refers to the cracking in riveted boiler plates made from steel, or as environmentallyassisted cracking eac. Sulfide stress cracking ssc vs hydrogen induced cracking hlc posted in refining, hydrocarbons, oil, and gas. Hydrogen embrittlement characteristics, especially pertinent to sulfide stress cracking, or steels has been investigated to a great extent. Hydrogen sulfide stress corrosion cracking in materials. Sulfide stress corrosion cracking occurs in presence of hydrogen sulfide. Tm01772016sg, laboratory testing of metals for resistance to sulfide stress cracking and stress corrosion cracking in h2s environments available for download testing of metals subjected to tensile stresses for resistance to cracking failure in lowph aqueous. Sulfide stress cracking ssc occurs at locations where atomic hydrogen is able to diffuse at sites of high internal stress, such as grain boundaries, inclusions and regions of triaxial stress at notches. Investigations of hydrogen embrittlement and sulfide stress cracking of nickel and nickelbase alloys have not been quite as extensive as in the case of steels. Our organization is offering a large array of sulfide stress cracking corrosion test service to our valued clients.
Sulfatereducing bacteria are active in the absence of oxygen anaerobic. Swris corrosion failure analysis helps clients create and improve corrosion management programs by sourcing knowledge from our. For this reason, along with toxicity risks of hydrogen sulfide gas, it is essential that water muds be kept entirely free of soluble sulfides and especially hydrogen sulfide at low ph. Micro alloyed pipeline steels are commonly used in the petroleum industry for transport applications 1.
Sulfide stress cracking of nickelcontaining lowalloy. Pdf sulfide stress corrosion cracking and hydrogen. Pdf detecting sulfide stress cracking and applying nace mr0175. Sulfide stress cracking ssc of high strength, low alloy steel is a phenomenon of particular. This type of cracking is referred to as stress oriented hydrogen induced cracking sohic. High atomic hydrogen concentrations in carbon steel can lead to sulfide stress cracking ssc of these hard areas. Hydrogen sulfide is a colorless, very poisonous, flammable gas with the characteristic foul odor of rotten eggs. Susceptible alloys, especially steels, react with hydrogen sulfide, forming metal sulfides and atomic hydrogen as corrosion byproducts. Nace mr0175 and mr0103 standards metals for sulfide stress. The influence of chemical composition and microstructure of api linepipe steels on hydrogen induced cracking and sulfide stress corrosion cracking. This term should not be confused with stress corrosion cracking scs, since this is anodic in nature.
Processes or conditions involving wet hydrogen sulfide, i. In the presence of oxygen aerobic, some bacteria may directly oxidize iron to iron oxides and hydroxides, other bacteria oxidize sulfur and produce sulfuric acid causing biogenic sulfide corrosion. Alloy b2 is damaged by intergranular stress corrosion cracking in the heat affected region when subjected to organic solvents comprising of sulfuric acid at 120oc. Us3585069a us3585069da us3585069a us 3585069 a us3585069 a us 3585069a us 3585069d a us3585069d a us 3585069da us 3585069 a us3585069 a us 3585069a authority us united states prior art keywords hydrogen sulfide reaction product cracking sulfide method prior art date 19671206 legal status the legal status is an assumption and is not a legal conclusion. As we know that both form of cracking are due to the absorption of atomic hydrogen that is produced by. Sulfide stress corrosion cracking and hydrogen induced cracking of a216wcc wellhead flow control valve body article pdf available in case studies in engineering failure analysis.
The environmental factors that increase the cracking susceptibility include higher temperatures, increased chloride content, lower ph, and higher levels of tensile stress. But, the presence of h 2 s in well fluids imposes severe restrictions on the use of tubular goods due to sulfide stress cracking phenomenon 2. I believe that studying complex phenomena such as sulfide stress cracking ssc of carbon and low alloy steels las requires a holistic historical perspective. Traditional austenitic steels are found to be more susceptible to such attack however duplex grades are less prone to it. Sulfide stress cracking is prevented by minimizing the hardness and strength of the alloys used. Webcorr provides corrosion consultancy services, corrosion expert witness and corrosion short courses for inhouse training, online and distance learning.
Sulfide stress cracking ssc occurs at locations where atomic hydrogen is. Scc can be attributed to the action of three important factors. Material selection for sour service environment pipeline. Corrosion, like all forms of failures, requires long term management for mitigation. Cold work effect on sulfide stress cracking of pipeline steel exposed to sour environments. H2s can cause sulfide stress cracking of stainless steels. Sulfide stress cracking ssc is a type of hydrogen cracking which presents a cathodic embrittlement mechanism. Sulfide stress cracking ssc is a form of hydrogen embrittlement which is a cathodic cracking mechanism. The authors conducted extensive analyses to explore the effects of metallurgical factors on the resistance of line pipe steels to hydrogen induced cracking hic and sulfide stress cracking ssc. The main observed corrosion products were iron sulfides and the typical damage associated with hydrogen sulfide presence was sulfide stress cracking ssc. Ssc is generally limited to steels having a hardness of 22 or greater on the rockwell c scale. Wet hydrogen sulfide h2s cracking inspectioneering.
For example, understanding the influence of microstructure on ssc resistance was made possible thanks, in part, to advances in electron and transmission electron microscopy. Tm01772016, laboratory testing of metals for resistance to sulfide stress cracking and stress corrosion cracking in h2s environments testing of metals subjected to tensile stresses for resistance to cracking failure in lowph aqueous environments containing hydrogen sulfide h2s. Sulfide stress cracking ssc resistance limits for a 125. Surface flaws also influence the hydrogen cracking or sulfide stress cracking of moderate to highstrength steels exposed to brine containing h2s. There are maximum acceptable h 2 s concentration limits in sale quality oil and gas, which require. However, hydrogen sulfide forms a weak acid when dissolved in water. Therefore, it is a source of hydrogen ions and is corrosive. Sulfide stress cracking nace mr01752002, mr0175iso. This increases atomic hydrogen diffusion, and causes a severe h2s environment. Sulfide stress cracking an overview sciencedirect topics. Sulfide stress cracking is a function of hydrogen sulfide concentration as low as ppm, hydrogen sulfide partial pressure, stresses, material yield strength, temperature and ph. Biaxial stress corrosion cracking frames capable of conducting testing in aggressive environments, such as brines with co 2 and h 2 s. The possibility that cold work affects the resistance to sulphide stress cracking is not unrecognised. Specialized stress corrosion cracking testing capabilities.
Sulfide stress crackingresistant drill pipe addresses h2s challenges. The obtained results indicate that the hydrogen sulfide is the most active gas in the corrosion processes that took place, quite above carbon dioxide. Sulfide stress cracking is also called hydrogen sulfide cracking, sulfide cracking, sulfide corrosion cracking and. In this chapter the terms eac and scc are generally interchangeable. Sulfide stress cracking ssc resistance limits for a 125 ksi grade high strength low alloy steel octg developed for mildly sour service. Standard material requirements materials resistant to. The major hazards of h 2 s are its ability to cause rapid damage to health or sudden death due to accidental exposure and metal integrity failure due to general corrosion or cracking. Detecting sulfide stress cracking and applying nace mr0175.
The effects of sulfide stress cracking on the mechanical properties. Sulfide stress cracking is the worst type of corrosion in the presence of hydrogen sulfide. Sulfide stress cracking nace mr01752002, mr0175iso 15156. Sulfide stress cracning is becoming a ney issue due to high levels of h2s and co2 in new natural. Environmentally assisted cracking eac is a general term that includes processes such as stress corrosion cracking scc, hydrogen embrittlement he, sulfide stress cracking ssc, liquid metal embrittlement lme, and corrosion fatigue cf. These services are rendered as per the exact client needs. Effect of coldwork on sulphide stress cracking resistance. Factors affecting each of the various forms of corrosion were also presented.
Also, atomic hydrogen dissolved in the steel lattice may embrittle areas of hard microstructures in carbon steel base metal or weldments. Sulfide stress crackingnace mr01752002, mr0175iso 15156 651 te c h n i c a l new sulfide stress cracking standard for refineries don bush, principal engineer materials, at emerson process management fisher valves, is a member and former chair of a nace task group that has written a document for refinery applications, nace mr0103. Gas phase water needs to be there as well even in a trace amount. Maintenance, monitoring and failure costs can be reduced when corrosion mechanisms are well understood and corrosion prevention techniques are applied in the specific environment. Among the most prone to sulfide stress cracking include valve trim, blowout preventer hard parts and tool joints. Sulfide stress cracking of pipelinecase history onepetro. Sulfide stress cracking ssc vs hydrogen induced cracking. Polythionic acid stress corrosion cracking deterioration. Sulfide stress cracking is also called hydrogen sulfide cracking, sulfide cracking, sulfide corrosion cracking and sulfide stresscorrosion cracking. Hydrogen stress cracking is a form of hydrogen embrittlement that occurs when corrosion from acids like wet hydrogen sulfide and hydrofluoric acid cause atomic hydrogen to penetrate hardened or higher strength steels and cause stress cracking. Corrosion problems during oil and gas production and its.
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